Sure, the simple answers are two fold. #1 they use FANTASTIC pumps to supply the skimmers. Remember, what any pump driven skimmer pump does is draw water and air into its intake, dice the air up into fine microbubbles, push these bubbles into a reaction chamber (hopefully swirling them around), allow some to go to the top of the collection cup and have the rest of the water return to the tank (hopefully without microbubbles). It is these microbubbles that do the work. The more bubbles you have, the longer they are in your reaction chamber, and the smaller these bubbles are is the largest limiting factor on a skimmer's performance. Sice of reaction chamber is great, but if you cant make good quality bubbles in the first place, you're SOL from the beginning, make sense?
There are two ways to create these microbubbles. MOST skimmers use plain old powerheads with square impeller blades to chop up the air like this one (thank you marine depot):
Most cheap pumps just come with these basic easy to manufacture blades. Now these big clunky square blades dont chop air up into very fine bubbles, they tend to make bigger bubbles which rise faster and collect less junk on their way up. However, a coralife or aquaC model will use a needlewheel impeller which has TONS of small fins and protrusious to really chop up air like this (again, thanks marinedepot)
So, impeller design is the first reason. The second reason is discharge control. If the skimmer is to operate at its full capacity, the skimmer outlet needs a very good method of control to get the water in the reaction chamber to be at the proper height. If the skimmer outlet is restricted (by means of a valve), the back pressure in the reaction chamber increases (since the pump is still pusing), and consequently the water in the reaction chamber will rise. This means that, the point at which bubbles rise to the surface and start spreading up the neck of the collection cup will rise. If this level gets too high, too many bubbles are ejected into the cup too quickly and it overflows. If the outlet valve on the skimmer is wide open and there is no back pressure on the reaction chamber, bubbles will not break high enough in the collection cup and instead fall back into the reaction chamber (bad cause nothing is skimmed out of the water column then).
The Coralife and AquaC models have fantastic skimmer outlet valves to allow you to really tweak the point at which the bubbles crest and therefore get the skimmer operating where you want it to. Most other hang-on models do not have such as good a valve.
There are two ways to create these microbubbles. MOST skimmers use plain old powerheads with square impeller blades to chop up the air like this one (thank you marine depot):
Most cheap pumps just come with these basic easy to manufacture blades. Now these big clunky square blades dont chop air up into very fine bubbles, they tend to make bigger bubbles which rise faster and collect less junk on their way up. However, a coralife or aquaC model will use a needlewheel impeller which has TONS of small fins and protrusious to really chop up air like this (again, thanks marinedepot)
So, impeller design is the first reason. The second reason is discharge control. If the skimmer is to operate at its full capacity, the skimmer outlet needs a very good method of control to get the water in the reaction chamber to be at the proper height. If the skimmer outlet is restricted (by means of a valve), the back pressure in the reaction chamber increases (since the pump is still pusing), and consequently the water in the reaction chamber will rise. This means that, the point at which bubbles rise to the surface and start spreading up the neck of the collection cup will rise. If this level gets too high, too many bubbles are ejected into the cup too quickly and it overflows. If the outlet valve on the skimmer is wide open and there is no back pressure on the reaction chamber, bubbles will not break high enough in the collection cup and instead fall back into the reaction chamber (bad cause nothing is skimmed out of the water column then).
The Coralife and AquaC models have fantastic skimmer outlet valves to allow you to really tweak the point at which the bubbles crest and therefore get the skimmer operating where you want it to. Most other hang-on models do not have such as good a valve.