If you can find the smaller bottle Prime is the best on the market, IMHO.
As for your 30% change not bringing down the nitrates considerably... of course it won't.
Let's go back to the math:
Let's say you are at 100ppm nitrates, and do a 30% PWC with tap water at 20ppm...
70% of the water would still be at 100ppm, and the new 30% would be at 20ppm.
So, 100ppm *0.7 + 20ppm *0.3 = 70+6 = 76ppm - a reduction of only 24ppm...
As pointed out, you will need to do a large WC every so often to really drop the levels... As I pointed out in my previous schedule, I do a 75+% change every 6 months. You would be due for one now. Here's where that would put you:
So, 100ppm*0.25 + 20ppm*0.75 = 25 + 15 = 40ppm... that's about as good as you can hope to achieve for now. I'd probably do ANOTHER 75% PWC in about a month's time. But, were you to do another one right away, here's where that would put you...
40ppm*0.25 + 20ppm*0.75 = 10 + 15 = 25 ppm.
Adding the extra plants as Snazy suggests will help to keep your nitrAtes from growing too quickly.... They will probably never be "perfect" but truthfully, I think you will be just fine with your fish. As TwoTankAmin pointed out, getting stem plants will be the best choice of plants to remove nitrAtes, but these will also use ammonia. Once again, this will put you in the situation of competing with your bacteria for the ammonia, BUT the difference between these plants and your chemical additives is that the plants will CONTINUE to use the ammonia, and not be "used up" like the chemicals will. You'll need to trim them from time to time, but don't trim them too aggressively at once and the ammonia will never be an issue. I'd say as long as you don't remove more than 20% of the plant matter at a time, you'll be just fine.
As for your 30% change not bringing down the nitrates considerably... of course it won't.
Let's go back to the math:
Let's say you are at 100ppm nitrates, and do a 30% PWC with tap water at 20ppm...
70% of the water would still be at 100ppm, and the new 30% would be at 20ppm.
So, 100ppm *0.7 + 20ppm *0.3 = 70+6 = 76ppm - a reduction of only 24ppm...
As pointed out, you will need to do a large WC every so often to really drop the levels... As I pointed out in my previous schedule, I do a 75+% change every 6 months. You would be due for one now. Here's where that would put you:
So, 100ppm*0.25 + 20ppm*0.75 = 25 + 15 = 40ppm... that's about as good as you can hope to achieve for now. I'd probably do ANOTHER 75% PWC in about a month's time. But, were you to do another one right away, here's where that would put you...
40ppm*0.25 + 20ppm*0.75 = 10 + 15 = 25 ppm.
Adding the extra plants as Snazy suggests will help to keep your nitrAtes from growing too quickly.... They will probably never be "perfect" but truthfully, I think you will be just fine with your fish. As TwoTankAmin pointed out, getting stem plants will be the best choice of plants to remove nitrAtes, but these will also use ammonia. Once again, this will put you in the situation of competing with your bacteria for the ammonia, BUT the difference between these plants and your chemical additives is that the plants will CONTINUE to use the ammonia, and not be "used up" like the chemicals will. You'll need to trim them from time to time, but don't trim them too aggressively at once and the ammonia will never be an issue. I'd say as long as you don't remove more than 20% of the plant matter at a time, you'll be just fine.