I have no idea what the precise range of the Senegal bichir is; you'll need to check Fishbase for that! Personally, I wouldn't worry too much about what particular rivers have -- concentrate on evoking the "feel" of a habitat, and choose the best species for that, even if it comes from the next river system along! Who'll know? It's the plants that really make the difference. A few months ago I was answering some similar questions on WetWebMedia for an American aquarist. He's since set up a stunning tank, and you can see a picture
here. The Anubias and Bolbitis really make it an identifiably African scene while helping to evoke a dark, forest river image.
For general community tank purposes, go with either the Senegal bichir or the fish traded as the marbled bichir
Polypterus palmas (likely one of a number of rather similar species). Both are tolerant and not particularly predatory, feeding primarily on invertebrates in the wild. They both have a good track record of being hardy and easy to maintain.
The tank you have should be fine for any of these fish. Do add a good canister filter or powerhead to beef up the water flow though; Congo tetras love a decent water current, especially in medium-sized rather than big aquaria. I'd be looking for 8-10 times the volume of the tank in turnover per hour.
Ctenopoma acutirostre is commonly traded, though sometimes under other names, such as leopard bush-fish or African leaffish. It's much better than any other leaffish, being easy to keep and willing to take frozen foods immediately. I kept one for at least ten years on mostly bloodworms with occasional chunks of prawn and live earthworm. Peaceful, hardy, doesn't get too big (about 15 cm in captivity).
Cheers, Neale