My tank is also a Rio 180, and unfortunately I live in a very high nitrate area. No matter how many water changes, it stays high!
I have tried the Juwel nitrate blue sponge - no change. Hope yours works better!
Change has recently occurred because I am running an external Eheim filter (I thought I would run this along with my Juwel one, as I am going to be swapping tanks soon, so thought I would get some good bacteria into my new filter for a few weeks before doing so).
Did a test recently, nitrates are still rather high, but have gone down significantly!
I am now thinking twice about whether or not to run an additional external filter with my Rio 180 after I move my cichlids into a larger tank.
Doesn't help you in the short term, but may be worth considering??
Hope he's OK.