A great thing about egg picking is you learn when you've gone wrong quickly. Feeding the wrong foods? No eggs. With the killies I have, only bug based flake (they don't like pellets unless I grind them up) produce eggs. But I get at best half the eggs I would with unprocessed foods. I can look at what I feed and see what they give.
The literature says Daphnia are great, and they are good. But for egg production, they are only so so. Freshly hatched artemia, bloodworms, white and grindal worms and especially mosquito larvae are better, by far. Many much hyped flake and pellet diets won't give a single egg.
When I had moderately hard water, at 140ppm, I got at best 2 eggs a day. When I moved to 80ppm, suddenly 5 was the new normal. That told me something. At 50ppm, after 20 years of never getting more than 5 eggs a day, I had days with 18 eggs in the mop.
Some eggs seem to have active chemical defenses against snails. I wonder if any of them can repel or be chemically invisible to other predators, like fish?
With the sheer number of killifish species, everything you say about them can be contradicted by nature. There are killies that need hard water, and others that can't live in it. Foods work differently for different species. Some species have digestive enzymes that only work efficiently in a 2 or 3 degree range, if not at an exact temperature. Others can handle anything. Some die if you cough in the next room, but 5 km from here, some Fundulus are living in a stream running though an old, active oil refinery, adapted to levels of pollution that astonish researchers.
Plus, if temperatures are between 15c and 24c, Aphyosemion eggs travel well in the mail. They really are amazing creatures, these eggs. I like them more when they become fish, but they are a good start.