Agree, but i have experienced a pH crash when nitrates have been 40/60ppm
Skins.
Not very scientifically conclusive, PH crashes can be caused by numerous things.
Tank is 39 galls, the pump is a powerhead with a under gravel filter.Fish 1 pleco' 6 clown loaches' 3 kissing gouramies' 4 sucker loaches'1 red tail shark'1 albino shark' 1 angle fish 3 guppies.Mark
First problem here is the under gravel filter, and is probably why you have high nitrate levels, due to the detritus building up in the substrate, I would switch to a large internal filter or an external filter. Also, the Pleco, what species is it? The Clown loaches will slowly out grow the tank but should be fine for a few years yet, but they do create a lot of waste, also the kissing gourami's will outgrow the tank, and probably the loaches too species dependant. The Sharks will probably fight as they mature, and they tend to become very aggressive also.