There's a big difference between carcinogenic chemicals like herbicides that kill people and animals, and a couple of drops of dechlorinator that usually consists of sodium thiosulphate, which people can drink and not die from.
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They don't always get it right. Remember, there are plenty of stupid people out there working in jobs that have hazardous materials.
Personally, I used to add the stated amount of dechlorinator and then add a couple of extra drops to water that I was holding. When I managed to get a chlorine test kit, I also used to measure the chlorine levels every week before adding dechlorinator. There were plenty of times I had to double and even triple dose my tap water with dechlorinator due to the excessive chlorine levels caused by stupidity at the water corporation.
If the OP has chloramine, that usually requires a higher dose of dechlorinator compared to chlorine. Most dechlorinators have one dose for chlorine and a double dose for chloramine.
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If you use a dechlorinator that neutralises chloramine and binds to free ammonia to make it harmless for a short time, you should add this dechlorinator to the tap water on the same day you use the water.
If you dechlorinate and aerate the water, then let it sit for a few days, the part of the dechlorinator that has bound to the ammonia can separate from the ammonia and it is no longer safe. You end up with toxic ammonia in the aquarium water, which gets used by the filter bacteria and converted to nitrate.
The filter bacteria will use the free ammonia pretty quickly (usually within an hour), but if the pH of the tank water is high (above 7.0), the ammonia can harm the fish.