TwoTankAmin
Fish Connoisseur
What you have just reported is simply not possible as far as I can see. Here is why.
1. You wrote you would add ammonia when your readings for ammonia and nitrite reached 0/0. When you wrote that your reported readings were 0/0.25.
2. You then said you would by adding "6ml ammonia, that should raise it to around 1.3ppm"
3. Using the chemistry involved to do the calculation, The most nitrite that 1 ppm of ammonia can produce is about 2.55 ppm (using API kits).
4. If you were dead accurate at 1.3 ppm of ammonia going in, then the maximum nitrite it can produce is 3.25 ppm. If you were off and had put in more ammonia than you had planned to get 5.0 ppm of nitrite would require just under 2 ppm of ammonia to start.*
5. Ammonia can only lose strength over time, not gain it.
6. If you had a some amount of nitrite oxidizing bacteria before as evidenced by earlier posts, they cannot all have vanished and left the ammonia ones intact.
*(assumes no live plants in the tank)
I do not know what is wrong here, but the numbers as reported do not make sense to me.
For the number crunchers out there:
-Atomic weight of ammonia as NH3 = 17.0305 and as NH4 = 18.0388. (Total ammonia is some of both in most tanks but even at pH 8.8, NH3 will be < 30%. I use 100% NH4 when doing calculations.)
-Atomic weight of nitrite (NO2) = 46.0055.
-Atomic weight of nitrate (NO3) = 62.0049.
Atomic weight of Nitrogen (N) = 14.0067, Atomic weight of Hydrogen (H) = 1.00794, Atomic weight of Oxygen (O) = 15.9994
FYI when using the nitrogen scale, 1 ppm of NH3 or of NH4 = 1 ppm N02 = 1 ppm NO3 because only the N ions are being counted.
1. You wrote you would add ammonia when your readings for ammonia and nitrite reached 0/0. When you wrote that your reported readings were 0/0.25.
2. You then said you would by adding "6ml ammonia, that should raise it to around 1.3ppm"
3. Using the chemistry involved to do the calculation, The most nitrite that 1 ppm of ammonia can produce is about 2.55 ppm (using API kits).
4. If you were dead accurate at 1.3 ppm of ammonia going in, then the maximum nitrite it can produce is 3.25 ppm. If you were off and had put in more ammonia than you had planned to get 5.0 ppm of nitrite would require just under 2 ppm of ammonia to start.*
5. Ammonia can only lose strength over time, not gain it.
6. If you had a some amount of nitrite oxidizing bacteria before as evidenced by earlier posts, they cannot all have vanished and left the ammonia ones intact.
*(assumes no live plants in the tank)
I do not know what is wrong here, but the numbers as reported do not make sense to me.
For the number crunchers out there:
-Atomic weight of ammonia as NH3 = 17.0305 and as NH4 = 18.0388. (Total ammonia is some of both in most tanks but even at pH 8.8, NH3 will be < 30%. I use 100% NH4 when doing calculations.)
-Atomic weight of nitrite (NO2) = 46.0055.
-Atomic weight of nitrate (NO3) = 62.0049.
Atomic weight of Nitrogen (N) = 14.0067, Atomic weight of Hydrogen (H) = 1.00794, Atomic weight of Oxygen (O) = 15.9994
FYI when using the nitrogen scale, 1 ppm of NH3 or of NH4 = 1 ppm N02 = 1 ppm NO3 because only the N ions are being counted.