Alkaline is above 7.0, Acidic is below 7.0.
Generally speaking the best course of action is to NOT change the water. What comes out of the tap is the best way to go with your water, especially as you are just beginning. If you find that your water is 7.5+, you have water that we would consider alkaline, and probably hard, as well. This knocks out many fish from your options, but opens up the African cichlids options... these are far more aggressive than the South American varieties, but are also the most colorful freshwater fish there are, in my opinion. Lake Malawi is the home to many of them. These are often referred to as "Mbuna". They require rocky tanks, not plants as they will destroy the plants. So, this type of tank might be something to look into.
S.A. cichlids, like apistogrammas are great looking fish, but smaller. They can easily be kept with Bristlenose Plecostomus (I believe that's the fish you were describing as the bristlemouth catfish). The BNs are great algae eater, but a bit reclusive. You won't see them much once they are full grown. As they are younger they eat so frequently that you almost always seem them somewhere. As they get older, they require less food, and come out more at night than during the day. I saw mine a bunch today, but that's rare - I also fed them far earlier in the day than usual, because its a weekend (and it was raining so I was stuck in the house).
Tell me your tap water stats and we can discuss some real options.
Generally speaking the best course of action is to NOT change the water. What comes out of the tap is the best way to go with your water, especially as you are just beginning. If you find that your water is 7.5+, you have water that we would consider alkaline, and probably hard, as well. This knocks out many fish from your options, but opens up the African cichlids options... these are far more aggressive than the South American varieties, but are also the most colorful freshwater fish there are, in my opinion. Lake Malawi is the home to many of them. These are often referred to as "Mbuna". They require rocky tanks, not plants as they will destroy the plants. So, this type of tank might be something to look into.
S.A. cichlids, like apistogrammas are great looking fish, but smaller. They can easily be kept with Bristlenose Plecostomus (I believe that's the fish you were describing as the bristlemouth catfish). The BNs are great algae eater, but a bit reclusive. You won't see them much once they are full grown. As they are younger they eat so frequently that you almost always seem them somewhere. As they get older, they require less food, and come out more at night than during the day. I saw mine a bunch today, but that's rare - I also fed them far earlier in the day than usual, because its a weekend (and it was raining so I was stuck in the house).
Tell me your tap water stats and we can discuss some real options.