This is not advisable, unless you can acquire a bonded mated pair. Discus are very similar to angelfish in this respect. They are shoaling fish that live in groups. They develop an hierarchy within a group placed in the aquarium, and having two, three or usually four rarely works because of their temperament. There are always exceptions, but it is better to assume the fish we acquire will be normal and not abnormal. A group of five or more should spread out any dominance, though again there are always the exception. Eventually a male/female pair may form, and then you are in another situation. Discus are generally not as rough as angelfish, but they are still cichlids and territory and dominance can be very strong.
On the size, Jack Wattley used to advise purchasing discus together at the 3 inch or maybe it was 4 inch size, to have better luck establishing the group hierarchy. No one knew more about discus than he did.
Another thing, if you did luck out with two or three "compatible" discus, adding a fourth and fifth later is really asking for trouble.