You can post ammonia, nitrite and nitrate but if the tank is cycling and you have a nitrite reading, then you will get an inaccurate nitrate reading because the nitrate test kits read nitrite as nitrate.
If the tank has cycled and there is 0 ammonia, 1ppm of nitrite and 20ppm of nitrate then that is pretty close to what the water test is, but if the tank is still cycling then you don't bother testing for nitrates until the nitrites have gone up and come back down.
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You should be adding the dechlorinator to a bucket of water, aerating it for at least a couple of minutes and then adding the dechlorinated water to the tank.