The rule I read is picking dried leaves from the ground, those that break when bent, not bend, are good for use.
They shouldn't have any spots, those could be mold.
I dry them in air or dry places with draft and never store them in plastic. Glass jars work great, linen bags work too. They last year's.
To avoid leaves staying on the surface, I take small jars, fill with water and leaves and keep them for weeks or months. Based on what i want the leaves for, i wash them before usage ( just for tanin and fish benefits) if i want to feed them to otos or snails, i keep the slime coat on. Some people use the water, but it is anorganic and full of rot. So I wouldn't.
Pouring boiling water on the leave will make it sink quickly, but the leave disintegrates way quicker than when presoaked. Oak leaves go quicker and are tastier than beech that lasts weeks longer to go. Summer oak is the best but good luck identifying it.
Picking alder cones is recommended, from trees directly. But I never seen one for real