This is another debatable point, plants using or not using nitrate.
Most aquarium plants prefer ammonia/ammonium, and will ignore nitrate if the ammonia/ammonium is in balance with all other nutrients and the light. They will not switch to nitrate (or nitrite) under normal circumstances (low-tech, natural method planted tank) because chances are the light and other nutrients (esp carbon here) will not be sufficient. And it takes plants about 24 hours to change gears. And, when they do, they have to then spend considerable energy changing the nitrate back into ammonium so they can use it. So, it is not surprising that they tend to ignore nitrate. [In high-tech systems it is very different.]
Diana Walstad goes into all this is great detail in her book Ecology of the Planted Aquarium, citing numerous scientific studies.
Also, there is denitrification. Bacteria that use nitrate to create oxygen. And, there is the change from nitrate to nitrogen gas that then escapes back into the atmosphere at the surface.