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What Is This On The Side Of My Tank?

It's hard to say, because we don't know how high your ammonia or nitrite might be.
 
I'd be tempted to do one large one to start with; leave just enough water for the fish to swim upright (don't forget to switch your heater/filter off first!) before refiling with warmed, dechlorinated water. That'll get rid of anything that's built up since you last did one.
 
Then do 50 or 60% every day until you can afford some test kits. If you get the shop to test the water, get them to write down the actual numbers for you; sometimes they'll just say, "it's fine", or "a bit high", which really doesn't help!
 
Best of luck; keep us posted on how things are going :)
 

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