Unfortunately I'd say three-spots (opalines, blue, goldens etc) are the most aggressive of the more common smallish gouramies.
Dwarf gouramies are some of the most peaceful, rarely bothering any other fish and showing most aggression only towards each other.
I would say it isn't a good idea though your tank's size, other inhabitants and decor do play an important role.
If you do go for it, I'd suggest a larger gourami such as a pearl or some other three-spot (trichogaster trichopterus) variant or possibly a moonlight gourami. Alternatively, thick-lipped gouramies (colisa labiosa) and colisa fasciata are similar to dwarfs in appearance but are larger and less fragile.
Also, are you sure your gourami is a male? Males have more pointed dorsals. If it is, he'll be more territorial than a female and you should make sure you don't add another male. I'd also suggest you go for 2 new inhabitants rather than only one - to spread aggression. And also re-arange your tank's furniture before you introduce the new fish - maybe take the original one out until the new fish has settled down or temporarily float him in a bag while you acclimatise and release the new fish - so that the old one doesn't feel like it's territory is being violated and both have time to get used to each other without either being at a disadvantage.
Good luck!