The limiting factor on sump size will be size of skimmer. It has to fit in the sump with enough room for pumps, water entry, etc. 10G will be tough IMO. You'd be better with a 15G rubbermaid, believe me.
Anyway, DO NOT use an overflow that relies on a pump. It WILL fail and you will end up draining your sump and flooding your floor. You are asking for trouble. If you haven't taken my advice you really, really need to look at reefcentral on issues like this.
The skimmer will have hookups but generally you want the overflow running through a pipe and into the sump, then have a small pump feeding your skimmer independent of the overflow pipe (so you don't overwhelm the skimmer). You'll just use a hose to return to the tank.
As for flow rate, overflow boxes are rated at GPH they move, as are return pumps. So you match (my overflow and returns are 700GPH). You should have a ball valve in the PVC to adjust if necessary.
Again, reefcentral will have whole articles guiding you step-by-step in setting this up.
Did you find the post on live rock for sale???
Jump on this one. This is a steal!!!
http/reefcentral.com/forums/showthread.p...threadid=281190