If you can rule out poor health as an issue, then adding more corys would probably help them get over their shyness. They are schooling fish and are less likely to be stressed when there is a larger number of them.
Until you find out if this is the problem, I suggest you wait to get gouramis, since these fish can behave in an aggressive way and make them feel even more threatened.
Until you find out if this is the problem, I suggest you wait to get gouramis, since these fish can behave in an aggressive way and make them feel even more threatened.