Question About The Science Of Co2

Not a specific issue or question about my aquarium, more of a curiosity.

My ideal situation would to be able to simulate a natural highly planted pool which needs very little tinkering/external influence from me in order to work. Which leads me to my question:

In the natural environment where does the CO2 needed for plants to flourish come from? I understand the chemistry of CO2 fertilization on land crops (I wrote my dissertation on it and could bore you for hours!), but I don't know what the natural source for it in the high levels suggested for a healthy planted tank.

Any ideas?

See here where I go every year:

redludwigiaIch2008.jpg

cryptsrainbow.jpg

Gatorstreamriverofgrass.jpg


These are all spring feed systems with high CO2 coming in from ground water, 10-30ppm ranges.

Unlike terrestrial plants, all aquatic plants are intensely limited by CO2 due to Fick's 1st law of diffusion, about 10,000x more limited.
Exchange rates are simply to slow.

I think the tank you are thinking about is the non CO2 planted system.
This is a more sustainable approach, the balanced approach that many seem to seek.
Many are drawn away from this due to the rapid growth seen in well gardened CO2 enriched aquascapes.

The rate is 10-25X slower growth however.
So now the fish waste and perhaps a tiny bit of ferts topping it off every 1-2 weeks is all that's needed, no water changes, and stable CO2, however, it 's much much lower now.

Key part is that CO2 is stable. Some comes in from the air above, some is present after night and bacteria and fish respiration etc have added a little bit higher than ambient levels in the air and none is being used up by the plants.
Another simple method is to use floating plants, or a small %, say 10-20%, that do not have any CO2 issues that the submersed plants have.

Here's a tank that has not had a water change in several years:
cubenonco21.jpg


But they trim the plants every so often(export of waste, add food(nutrients)), clean filters etc.
So there are things coming in and out of the system, but not a lot.

They cannot add more and more fish, or do lots of water changes, disturb the balance etc, plants can and will adapot to lower CO2 by using less carbon in some structures and also by producing more Rubsico to sequester what little CO2 there is, and some species of aquatic plants will use bicarbonate and strip the KH for a carbon source.

So there are few sources.

When you add CO2 at 10X, then you get a lot more growth lie industrial style high yield agriculture. Not particularly natural, but there are a few places like that that are also very stable(florida, Brazil, Texas all have some very nice exmaples of spring fed systems full of rich aquatic plants and fish at high CO2 ppm's.

Regards,
Tom Barr
 
Thanks for an excellent, informed discussion guys this is exactly what I was after. Tom, you've cleared a lot of what I was wondering up so thank you very much for that.

I am going to go away, do some planning and draw up a battle plan of how to approach this project. I'll be sure to report back with pictures.

Also this has been my first real couple of days on these forums other than asking for the occasional bit of help, but I'm going to make an effort to stick around and shove my ore in wherever possible!
 
I honestly believe Colin's heart is in the right place here.

I guess I should be a little more diplomatic. :X

The problem is that this thread will fall off the end of the page and be forgotten, and the same tired comments will prevail once again. :-(

Dave.
 
for crying out loud and stop trying to hold back the planted side of the hobby. You clearly know precious little about it.

probably the most paranoid comment i have yet to read on forums. and all because someone has a different view. humm, who "is" holding back the hobby, I wonder?
i read, that "experts" used to say water changes were a bad thing, were those who said they were not, holding back the hobby?
 
for crying out loud and stop trying to hold back the planted side of the hobby. You clearly know precious little about it.

probably the most paranoid comment i have yet to read on forums. and all because someone has a different view. humm, who "is" holding back the hobby, I wonder?

:lol:



i read, that "experts" used to say water changes were a bad thing, were those who said they were not, holding back the hobby?

This is an informative thread; try reading it, such as below.

Key part is that CO2 is stable....

Here's a tank that has not had a water change in several years:
cubenonco21.jpg


They cannot add more and more fish, or do lots of water changes.....

Regards,
Tom Barr


Water changes are a horses for courses operation, but you already knew that before writing such a general statement didn`t you?

Dave.
 
I don't think it's a case of differing points of view when 1 view is wrong and now is known to be so.

Would we not shout down anyone who said smoking was good for you because someone still believes what they were told during the war? Would we just say thats your point of view if I said all my grandparents smoked and they lived well into their 80s and therefore belittled any suggestion it was not good for you? Of course not.

this may not be as clear cut as my extreme example but the planted side as we see it now is still quite a young hobby and what used to be the norm and believed by all was in the days before high efficient lighting, CO2 injection and no fear of nitrates.

People just used to believe everything the governments environmental people said and translate it straight into the aquarium.

When every government's scientists blame fertilisers for their green waters without taking into consideration that when they dredge all the plants out every month 'to make it look prettier' they are disturbing nature themselves and actually removing the natural cure for the problem they don't want!!!

Then people say 'it's different in the aquarium'. Yes it is. We add plants and combat algae. Governments (via localised agencies) remove plants and get algae. But of course if they want to keep on about fert runoff then that achieves their other goal of reducing fertiliser usage without annoying the farmers by banning it for other reasons like the EU is doing at the moment ;)

AC
 
I still stand by my remarks about nutrient run-off causing algal blooms in our rivers. Our Australian rivers have evolved to use the sunlight, water movement (or lack of) and CO2 in the atmosphere, but they never evolved to use the excessive nutrients that are currently going into them. For thousands of years there has been little nutrient added to our systems and then in the last 50years vast quantities have made it into them. This has thrown the balance out of whack and that is what causes the algal problems.
The planted tank (EI) system rellies on a balance between the 3 things plants need, light, nutrients and carbon. If one of these is in excess, or is lacking, then problems occur. The same thing happens in our rivers because we are adding more nutrients and creating an imbalance.

-----------------------------------------------

For Dave Spencer

When I go back to freshwater I will set up a plant tank and post pics on here. Until then I will stay with my corals as they are more interesting with their animal/ plant symbiosis.
 
The planted tank (EI) system rellies on a balance between the 3 things plants need, light, nutrients and carbon. If one of these is in excess, or is lacking, then problems occur. The same thing happens in our rivers because we are adding more nutrients and creating an imbalance.

Not even close ColinT

The EI system rellies on dosing excess nutrient and dosing excess CO2. This makes the system non limiting. We then redress the leftovers each week with heavy water changes.

Therefore each day there are nutrients left over for algae to jump on if you believe that excess nutrients cause algae. This is why we can safely say to people excess nutrients do not cause algae. Why because we add excess every day.

People who blame the excess nutrients either believe old theories without looking at the evidence against or are assuming it is the excess nutrients.

Dosing not enough nutrients or CO2 will result in algae. Not the other way around unless someone is dosing the nutrient and for reasons (normally circulation issues) the plants are not receiving the nutrient.

I dose 20ppm of Nitrate and 5ppm of Phosphate into my tank. How much is still in there? I don't know because I don't test. Why do I not test? Because hobby kits are pants in general plus I know what I added and therefore I know the plants have enough. Then at the end of the week I change 50% water.

Like I said before I have breeding Corys and an out of control breeding colony of shrimp. I don't see any problem there due to water quality!!!

I await the freshwater setup. Will be interesting to see. I did however guess you were a reefer.

AC
 
I'm not a reefer as such. I happen to be working with corals currently because I lost all my freshwater fishes to TB. Now I breed corals to help ease the collection of wild stock.
 
I just assumed because its a very common thing when reefers move into freshwater and then onto planted that they bring their 'control and test' methods across and worry about Ph, nitrates & phosphates too much.

Both fish and both water but vastly different systems. :good:

AC
 
I honestly believe Colin's heart is in the right place here.

I guess I should be a little more diplomatic. :X

The problem is that this thread will fall off the end of the page and be forgotten, and the same tired comments will prevail once again. :-(

Dave.

Oh, you know me better than that too.
I come across pretty much barbaric most times.
So savor it for the rare thing that it is :blush:

hehe

Regards,
Tom Barr
 
I still stand by my remarks about nutrient run-off causing algal blooms in our rivers. Our Australian rivers have evolved to use the sunlight, water movement (or lack of) and CO2 in the atmosphere, but they never evolved to use the excessive nutrients that are currently going into them. For thousands of years there has been little nutrient added to our systems and then in the last 50years vast quantities have made it into them. This has thrown the balance out of whack and that is what causes the algal problems.
The planted tank (EI) system rellies on a balance between the 3 things plants need, light, nutrients and carbon. If one of these is in excess, or is lacking, then problems occur. The same thing happens in our rivers because we are adding more nutrients and creating an imbalance.

-----------------------------------------------

For Dave Spencer

When I go back to freshwater I will set up a plant tank and post pics on here. Until then I will stay with my corals as they are more interesting with their animal/ plant symbiosis.

I would also, particularly when those streams lack plants and buffer zones, most of which get destroyed when farms are put in, and the natural water ways that have had the water normally very limited in N and/or P are suddenly altered dramatically by humans. I'll be the first guy screaming about it. I also know how to regulate and add buffer zones and water shed management to reduce such impacts. You will not stop farming etc, so we have to do something that can manage both issues so some farming is still done, but careful environmental considerations are implemented as well, in the past, there was no to very little regard for natural ecosystem functioning or resources. Fortunately, things are changing, a bit slow, but they are slowly changing.

Depends on which system you are speaking of for higher nutrients, for example, the Florida Everglades has been highly impacted by PO4, causing larges plant community shifts, Calidium (native) Typha(non native in these new locations), so they are trying to use wetland management as filters to remove the PO4. This also involves water shed dynamics as well. Big issues and huge billions and billions of $ spent and more every year.

This is not something they have not thought a lot about and done a great deal of research about.
There are quite a few that have argued that removal of PO4 is not going to give the results that they seek, rather, restoring the water seasonality and level changes that flood control implemented and drainage for farms, irrigation etc.

Many lakes and swamps have high loads, but still are fine. Others are severely impacted.
It really depends on many factors before we can say any one thing.

Ironically, many regulators have left PO4 bans in place, I think that's good even with such research that questions the validity of the PO4 ban.
Won't hurt, but when it comes to restoration ecology, success is rare overall.
We think it might be one thing, often times it is not.

Aquariums however are much simpler and easier, we have complete control here. We have a tank full of hungry fast growing weeds, if you add high light and CO2, you can bet they will go through a lot of nutrients.
If you want to learn about algae, you need to learn how to induce and grow it well. It needs to be done on purpose, not just trying to run and avoid it.
Otherwise folks end up wasting time, $, and effort doing things that never resolve the root issue. Aquariums, lakes, pools, etc. Stagnant pools are part of natural systems also, they are not always stagnant either, they get flushed out every rainy season.


EI is pretty wide as far excess ranges.
I've never found any upper bounds for PO4 that's practial or human error might do for planted tanks, many have added KH2PO4 instead of KNO3 for example with out any ill effects, 5-10ppm seems to have no impact. It's not toxic either. KNO3, mostly NO3, I've gone to 160ppm for some time, others have gone to 80-100ppm for weeks, months without any issues.

A good upper bound for plants might be in the 80ppm range, and a normal range of 10-30ppm is more typical using the method.
You can do more water changes and large %, say 70% or do 50% 2x a week and maintain and closer range, say 10-20ppm, or even less. You cxan do fewer water changes, but now your error rate goes up. Always a trade off.
It's not set in stone, it's just an old method folks have done + a little math to factor in the % dilution for the water changes based on the ppm's added for the week etc.

Old timers have been doing it for years.

It's particularly useful if you do not test the water and if you do the water changes anyways to prune and trim without sloshing water everywhere.
Most hobbyists get lazy and do not test, many know they "should" at least according to dogma, but don't.
This issue with a method tends to be more Social than Plant Science.

Light and nutrients can be ruled out fairly easy, CO2 cannot, so we factor in light and then apply non limiting nutrients, then we can test+ eyeball CO2 the rest of the way.
I wish I could suggest a simple accurate CO2 method for testing, but eyes are about the best solution.

Accurate dissolved CO2 Meters run 3000$ up to 8000-10000$.
So I'll use the eyes and rule the rest out.

That's not too bad and then you soon realize how huge the issue with CO2 is and how if can influence all the other nutrients etc in our tanks.
CO2 is very much a two edge sword for the hobbyist, it helps the hobby and the grower, but also causes about 95% of all the algae issues.
Sort of like large scale farming, we like the food and cheap cost, but complain about the environmental effects.

Need a good way to mitigate both.

Coral breeding is actually pretty fun and interesting.
I like macro algae and marine plants.

My client's reef tanks are doing mighty good.
You might find the algae scrubber methods much more to your liking than skimmer based systems of refugiums for Macro algae(I like macros for many yreasons, but they are more difficult to care for than the noxious algae that grows on the turf scubbers) I do not treat macro algae/seagrasses as utilitarian plants, but the noxious microalgae and hair algae, I certainly do:)
"Santa Monica" usename has some long threads on several web sites about it and the results.

Use the plants to clean your systems, they are quite good at it.

Regards,
Tom Barr
 
Other folks have made some comments about large frequent water changes using EI as "bad, wasteful, not ecological inded" but these same criticisms need to be leveled at ADA's methods, which employ the same, as well as any Owner of Discus, and other fish that are feed a lot and need high quality water, such as breeders that raise fish.

Like breeders, we use simple methods to grow lots of plants easily, which we sell to the trade, rather than growing them in Singapore, or with hydropnics here, shipped etc, which is wasteful.
Like a famrer's market, think global, buy and grow local.

This is more sustainable than vendor's selling you the products. Who knows what they do with the water?
You can easily control what is done with/where that water goes.
I use it for the landscaping, I use no tap water with chlorine for the landscaping, this aids the bacteria and cycling of compost for the yard. It can also recharge ground water supplies.

Wastewater is not "waste", it may be used for many things.
If sustainable approaches and less water use is the goal, then install efficient toliets (largest use of water in most homes), install an efficient clothes washer, dish washer etc.
Add a low flow aerator shower head, saves about 4 liters/min. Do not use RO water, waste 90% of the water as rejection. poor irrigation systems for lawns and landscaping, use smart irrigation timers that can sense the evapoiratransipration rates and add water accordingly, rather than when it is raining :sick: No water from irrigation of landscapes should end up in the storm drain,m this causes many orders of magintude than any of the risk associated with EI or planted tank use. You also should use less light as electric cost are the largest cost issue for most aquarist.

These things will reduce the load of water used and reduce cost and do far more to protect the environment.

I think Colin is certainly advocating this approach, as do I.
But we should also look at things a bit more holistically and where we can cut out waste and the trade offs we accept for saving more water/reduced electrical cost etc for this luxury hobby we like.
No one needs this "hobby", it is a luxury item. So bear that in mind, and you can more than make up for it focusing on other environmental and money saving approaches to reduce waste.

I recycle about 95% of the waste I generate. Not bad.

So I really have an issue when folks come at me or EI with this waste ecological baloney, while they miss the larger issues.
I know aquariums are a luxury item, as such I try to reduce the waste and get the results I want with less labor. Test kits are another way, but what of the toxic reagents used? Are they correctly disposed of? No!
They are typically all dumped down the drains. They also introduce and whle other set of assumptions and time weasting issues many aquarists simpy, do not care about, we get into this hobby to have a nice aquarium with plants etc, not to learn how to do testing of water. Who gets into this hobby to do that?

Never met any one yet.

Still, I honestly do not buy the environmental argument baloney against EI. It's Hippycritcal :rolleyes:
You should go after the high light folks and then the folks using test kits, and folks who own more than say 5 aquariums, those who do not reuse the wastewater, consider no aquariums at all! Go after ADA and Amano for suggesting 50% weekly water changes or more, promote only non CO2 sustainable slow growth, min light tanks. Like the one example I posted etc. But you need to be fair and look at the trade offs, see where and what can be done to reduce the usage etc of not just water, but all inputs and outputs. Many simply do not care that much about that, that's their choice also. If you do and that is an important issue to you, then go non CO2, particularly if you have a CO2 tank. Then you can see the other side's point of view and how well it works and how easy it is once you learn patience. If you can master several methods, then you can fairly evaluate each of them. If you have only mastered one, then that is the only one you can say much about really.

If you have not mastered any method, well, you cannot say anything about any of them :good:
Maybe later............

CO2 is a two edged sword.


Regards,
Tom Barr
 

Most reactions

Back
Top