It looks like bacterial fin rot which requires antibiotics. I know in the UK the med situation is awful. What you tried so far will not help with this. If you do not treat the fish, expect things to continue to degenerate.
Your bully angel wants to be the boss of the group, It may simply never be willing to tolerate things otherwise. With angels number my mute agressin for a but, But when a pair forms and is ready to get jiggy, it will all fall apart.
Mine were in a 45 gal. which is smaller than your 90, but I am still not sure if this is big enough to matter once you get a pair. Nor can one assume other fish in the tank will be safe. Angels are still cichlids and they will often drive off or kill other tank inhabitants when spawning and tending young.