Well, it will remain a mystery I guess. BTW, you didn't post the GH and KH as I initially asked, this might tell us something. And another thought occurs to me; as another member correctly pointed out, water chemistry changes will be more rapid in smaller tanks. The tanks may run lower than the tap water (mine do), but a water change will cause a higher rise in pH in a small tank, whereas in a larger it may not even shift due to the greater biological stability.