Sorry to hear you went through that experience Carecalmo but glad to hear you have been doing water changes, they are the first thing a good freshwater fishkeeper turns to in time of need or doubt usually.
Let's talk about water changes so the technique can be improved right away and for the future. There's nothing wrong with very large water changes (in rare cases where a tank has been almost completely neglected for more than a year or more it could be different but I doubt that's the case for you) and indeed, its very large changes that are needed to combat nitrite(NO2) especially!
Its important the very large changes be done with better technique as you are making a rapid change to the environment the fish are used to. The return water (tap water) should be treated with a good conditioner (product to remove chlorine/chloramines) dosed at 1.5x to 2x whatever the instructions call for (but not more than about 2x.) The return water should be temperature matched. This can be done roughly using your hand, that's good enough but its good to put your hand back and forth several times between the fresh tap water and the old tank water to get a feel for whether its right.
The -removal- of the old tank water is quite important. It should be done with a common gravel-cleaning siphon which is a siphon tube that has a clear cylinder on one end for churning up the gravel. This plays an enormous role in pulling the organic debris out of the substrate where it is in the process of breaking down into ammonia and can be overwhelming the tank ecosystem if allowed to sit there too long. This is why we perform this type of weekly maintenance. In a tank that is showing nitrite(NO2) levels above zero ppm, it could be that this substrate debris is at a bad level or is just at a level that overwhelms the not-yet-big-enough beneficial bacteria in the filter. When you plunge your clear cylinder deep in the gravel and hold it there, you can sometimes see a cloud of debris slowly move up the cylinder like dust. The chemical charges in this organic debris can attract nitrite(NO2) and nitrate(NO3) and thus it may be abnormally high in the substrate.
When your nitrite(NO2) gets close to 0.25ppm (or higher) then the fish will be much more damaged or stressed by that nitrite poisoning than they would be by any effect of a large water change. The water change will be a life-saver in that case.
Your pH of 6.2 is quite low for bacterial growth, but I think its important that the large water changes be tried for a while (and please show daily stats of ammonia, nitrite, pH and nitrate here in your thread for the members) before anyone recommends any extra action regarding that.
~~waterdrop~~