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Mega-powerful Nitrate And Phosphate Remover Replaces Skimmer, Refugium

Well I thought it couldn't grow any more in two weeks, but this time it reached the top of the window and was getting ready to spill out the end. My other scrubber was not very grown yet, so I did not want to clean this one today, but I thought I better before it spills. Tests today were N02=0, NO3=2, P=.015? (very faint blue). Feeding is one silverside per week to the eel, 4.8 ml/day continuous feeding of Oysterfeast for the corals (very low amount, currently), and misc nori/daphnia for the fish. Pics:


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Video:

http://www.youtube.com/watch?v=LJxzeAgOS_M
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Finally getting the 25 nano scrubber to have consistant results. Am testing one side of it here, on a FW 10 gal with some tetras, catfish, suckerfish, and a discus. 0, 0, 0, when feeding one frozen cube blood worms a day. No water changes, and top off with tap water (no chlorine remover added)...

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Great Barrier Reef Aquarium

Many people who have not built a scrubber properly (after August 1988) often say how the Great Barrier Reef aquarium was a scrubber "failure" because the corals did poorly. Apparently these people have not done much reading. In the early days of that aquarium, the scrubber was doing it's job great:

1988:

Nutrient Cycling In The Great Barrier Reef Aquarium
http://www.reefbase.org/download/download.aspx?type=10&docid=10506

"The Reef Tank represents the first application of algal scrubber technology to large volume aquarium systems. Aquaria using conventional water purification methods (e.g. bacterial filters) generally have nutrient levels in parts per million, while algal scrubbers have maintained parts per billion concentrations [much lower], despite heavy biological loading in the Reef Tank. The success of the algal scrubbers in maintaining suitable water quality for a coral reef was demonstrated in the observed spawning of scleractinian corals and many other tank inhabitants."

But did you know that they did not add calcium? That's right, in 1988 they did not know that calcium needed to be added to a reef tank. Even five years after that, the Pittsburgh Zoo was just starting to test a "mesocosm" scrubber reef tank to see if calcium levels would drop:

1993:

An Introduction to the Biogeochemical Cycling of Calcium and Substitutive Strontium in Living Coral Reef Mesocosms
http://onlinelibrary.wiley.com/doi/10.1002/zoo.1430120505/abstract

"It was hypothesized that Ca2+ and the substitutive elements Sr2+ and Mg2+ might [!] have reduced concentrations in a coral reef microcosm due to continuous reuse of the same seawater as a consequence of the recycling process inherent in the coral reef mesocosm."

"The scleractinians (Montastrea, Madracis, Porites, Diploria, and Acropora) and calcareous alga (Halimeda and others) present in the coral reef mesocosm are the most likely organisms responsible for the significant reduction in concentration of the Ca2+ and Sr2+ cations."

"Ca is not normally a biolimiting element, and strontium is never a biolimiting element; HCO3 [alk] can be. It appears that, because of a minor [!] limitation in the design parameters of the mesocosm, these elements and compounds may have become limiting factors. [...] It is surprising that the organisms could deplete the thousands of gallons of seawater (three to six thousand) of these elements even within two or more years [!!].

"The calcification processes are little understood."

So then in the late 90's, the Barrier Reef aquarium start using up it's supply of calcium, and the folks there said "the corals grew poorly". Really. No calcium, and the corals grew poorly. So they "removed the scrubbers" and "experimented with the addition of calcium" sometime after 1998. Then in 2004 it "definitely improved a lot". Really.
 
Low-light Scrubbers

Here is something new, different, and untested. I have not built one yet, but it should work for either SW or FW if the size and flow are correct. It is a vertical scrubber that you hang on the wall, and it requires NO electricity. It is a "low-light" scrubber:

LowLightScrubber.jpg





I got the idea when reading a study about algae growth in freshwater streams:

"Algal Response to Nutrient Enrichment In Forested Oligotrophic Streams". Journal of Phycology, June 2008. http://www3.interscience.wiley.com/journal/120083425/abstract

"Algae inhabiting forested streams have the capacity to acclimate to low light intensity. These light conditions affect their photosynthetic efficiency, but do not impair growth rates, in particular, in the case of thin diatom-dominated communities."

In other words, they don't filter as much per square inch (or per square cm) of area, but they do operate on very low light. Apparently it is mostly diatoms that grow in these low-light conditions.

The advantage of a scrubber like this should be obvious: It requires no electricity to power the screen. It still requires a pump, however, since the top of the scrubber would (probably) be high above the top of the tank. The scrubber is designed to operate on the light already available in the room, which would vary greatly depending on how strong the light bulbs are in the room, and how much sunlight comes in through the windows. The more average light the room has, the smaller the scrubber can be. The less light, the bigger it needs to be. Basically, the scrubber uses more area to make up for less light. And since the light is so low, the type of algae that is able to survive is (apparently) mostly diatoms.

Just as with regular scrubbers, the wider the unit it, the more flow is required. So in the spirit of keeping it from consuming too much electricty, a smaller pump could be used if the unit were narrow and tall. But the bottom of the unit will need to drain into either the tank or the sump, so there will be a limit to how low the bottom can be. And the limit to the top will be the ceiling. A tradeoff will need to be made, maybe so that it looks like a vertical picture on the wall. Fortunately the flow does not need to be as much as a regular scrubber, since it is one-sided only.

It will have to be experimented with to see if a clear cover is needed to stop any water dropletts from splashing out. Many people have decorative waterfalls of the same size as these, and they have no cover on them, so maybe water dropletts getting on the floor will not happen. Evaporation would be high though, and this might be reason enough to consider a clear cover.

Cleaning could (apparently) be done by having a removeable screen or porous sheet, just like a regular scrubber has. It would be big though, and would drip as you took it out. Also it probably would not fit into a sink, and so would need a bathtub or shower (or outside) for cleaning. A possible fix for this might be a very flexibe woven plastic mesh, which you could fold up like a towell and easily clean in a sink. A material like this might not lay down flat when it's in the scrubber, however.

This type of scrubber would be easiest to try for somebody with a cement floor, lots of wall space, open widows or skylights, a low sump, high ceilings, and a big sink or patio for cleaning. I have no idea of the size required for the unit.
 
New Feeding Guideline:

Each cube of frozen food you feed per day needs 12 square inches of screen, with a light on both sides totalling 12 watts. Thus a nano that is fed one cube a day would need a screen 3 X 4 inches with a 6 watt bulb on each side. A larger tank that is fed 10 cubes a day would need a screen 10 X 12 inches with 60 watts of light on each side.
 
Although almost no aquarist knows this (athough every marine biologist does), algae produces all the vitamins and amino acids in the ocean that corals need to grow. Yes these are the same vitamins and amino acids that reefers buy and dose to their tanks. How do you think the vitamins and amino acids got in the ocean in the first place? Algae also produces a carbon source to feed the nitrate-and-phosphate-reducing bacteria (in addition to the algae consuming nitrate and phosphate itself). Yes this is the same carbon that many aquarists buy and add to their tanks. In particular, algae produce:

Vitamins:

Vitamin A
Vitamin E
Vitamin B6
Beta Carotene
Riboflavin
Thiamine
Biotin
Ascorbate (breaks chloramines into chlorine+ammonia)
N5-Methyltetrahydrofolate
Other tetrahydrofolate polyglutamates
Oxidized folate monoglutamates
Nicotinate
Pantothenate


Amino Acids:

Alanine
Aspartic acid
Leucine
Valine
Tyrosine
Phenylalanine
Methionine
Aspartate
Glutamate
Serine
Proline


Carbohydrates (sugars):

Galactose
Glucose
Maltose
Xylose



Misc:

Glycolic Acid
Citric Acid (breaks chloramines into chlorine+ammonia)
Nucleic Acid derivatives
Polypeptides
Proteins
Enzymes
Lipids


Studies:

Production of Vitamin B-12, Thiamin, and Biotin by Phytoplankton. Journal of Phycology, Dec 1970:
http://onlinelibrary.wiley.com/doi/10.1111/j.1529-8817.1970.tb02406.x/abstract

Secretion Of Vitamins and Amino Acids Into The Environment By Ochromanas Danica. Journal of Phycology, Sept 1971 (Phycology is the study of algae):
http://onlinelibrary.wiley.com/doi/10.1111/j.1529-8817.1971.tb01505.x/abstract

Qualitative Assay of Dissolved Amino Acids and Sugars Excreted by Chlamydomanas Reinhardtii (chlorophyceae) and Euglena Gracilis (Euglenophyceae), Jounrnal of Phycology, Dec 1978:
http://onlinelibrary.wiley.com/doi/10.1111/j.1529-8817.1978.tb02459.x/abstract
 
If you are a U.S. patent attorney versed in foreign utility applications, please contact me about possibly working together on both published and unpublished utility designs...
http://www.algaescrubber.net/forums/viewtopic.php?f=2&t=833
 
Well it took a while to get time to take more pics, but here are the updated ones of my 100 gallon tank. The main thing to mention is that this tank is not for showing... it is for experimenting. Details are at the end of this post. There have been no waterchanges since August 2008. The only dosings are Mrs. Wages Pickling Lime in the top-off (for Cal and Alk), Seachem Reef Advantage mag, and Seachem Reef Advantage strontium. Feeding is 48 ml of skimmate... I mean... blended oysters, per day, 20 square inches of nori per day, and one silverside per week (for the eel). There are no mechanical filters, no chemical filters, and no sand. The only filters are the live rock (now 5 years old), and the algae in the scrubbers. The lighting is 2 X 150 watt halides, and one 96 watt actinic. The tank is 30 inches tall. Tests are Nitrate and Phosphate = 0 (Salifert), pH = 8.3 to 8.6, and the water is contantly filled with food particles:



High-Res: Click here
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continued...

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continued....

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Videos:

Whole Tank:
http://www.youtube.com/watch?v=xUl8FIQAxr0

Tank Right to Left:
http://www.youtube.com/watch?v=58pOisX2vSs

Eel Eating:
http://www.youtube.com/watch?v=kDZtHf-xXCc

Flower Pot:
http://www.youtube.com/watch?v=MMdllQSKU2c

Frag Tray:
http://www.youtube.com/watch?v=AtvF0ZbVX7w

Liquid Feeder:
http://www.youtube.com/watch?v=iOIx09XWYCo

Tube Anemone:
http://www.youtube.com/watch?v=p7TnVm19td4



Here were the main experiments:

Iron Overdosing: I tried adding an iron supplement for many years, but never saw any affect. I always followed the instructions, such as Kent's Iron+Manganese "Add two teaspoons per 100 gal, per week". It had no visible effect. But after I started to read the literature about algae and iron, and after I realized that I now have much more algae in my system that the average tank does, I went out on a limb and poured in 8 ounces of Kent's. This is 24 times the recommended dosage for 100 gallons. But I reasoned that it's not the gallons that matter, it's the amount of algae. And it worked. The algae in the scrubber, that previously was yellow and hard (due to lack of iron), turned solid green and fluffy. Growth was much faster that week too.

So if more was better, much more should be much better. So I poured in a HALF GALLON of the Kent's. This is 225 times the recommended dosage, and over 9 times more than what I put in before. This was the biggest mistake I've made yet on this tank (coral-wise). Within a few hours, both of the bubble corals shrank up to nothing, and started letting pieces go. The next day, my 3 year old 5" litho was half gone. And by the end of the week about 30 of my 60 corals were completely wiped out. Iron was even beginning to deposit on the inside of the tubing that feeds the scrubbers. Well, I never did a waterchange, and things have gone back to normal, but now I know the power and the problems of adding iron. The more algae you have in a system, the more iron it can use; but don't add too much. How much is too much? The green soft corals (like a green bubble) seem to be affected first, so watch those.

Over Feeding: When my scrubber (only one unit at the time) was basically not filtering at all (before I knew about pumps clogging, and lights getting weaker), I increased feeding to 128 ml of skimmate... I mean blended oysters... per day, along with 5 frozen cubes per day, and one silverside per day. No waterchanges of course. So with this high level of import, and with almost no export, nuisance algae began to explode in the tank. I must say, the few SPS I had really grew at that time. The over feeding made up for the small 150 watt halides in a 30 inch tall tank.

Non Feeding: After realizing the non-flow in the scrubber (due to the clogged pump), and the worn out lights in the scrubber (should have been replaced 9 months earlier), I got the export back into operation. But to speed up the removal of the nuisance algae in the display, I stopped all feeding for 2 months. No blended oysters, no nori, no cubes, nothing. Only one silverside for the eel, but only every 2 weeks. Well, another big lesson learned: If corals have been growing based on high amounts of food in the water, they cannot survive on less. In other words, if the food in the water was always low, the corals would not have developed a need for food. But since they were fed large amounts of food for a while, they grew and needed those large amounts at all times. When the feeding was stopped, I lost about 4 corals in the first 4 weeks, and another 10 corals in the next 4 weeks.

So the pics you see are what's left after the iron, the over feeding, and the non-feeding. I don't recommend these tests for anyone else; I did them so that I would be able to recommend safe feeding and filtering methods for others.
 
Success updates...

Trichome on the CR site: "I took my skimmer out of my 29g sump about 2 months ago. Since then i have not done a water change...I know i should but i am bad about that. I NEVER have to clean my glass in my DT. I don't take water parameters so i can't tell you what mine are, but i do know i don't get any algae in my tank other than bubble algae. I harvest one side of my scrubber about every 2 weeks [needs to be more often]. The water must be pretty clean because my 2 golden striped maroon clowns have spawned, for their first time, about 1 month after i took my skimmer out. Not only are there several people in Cincinnati trying algae scrubbers with great success there is a 50 page thread of people with great success too. 6 month update: I have had my turf scrubber going on my 29g tank for 6 months now without a skimmer. Currently i have 2 Gold Stripped Maroon clownfish, a Yasha gobie, a sixline wrasse, 2 cleaner shrimp, and a candy cane pistol shrimp in the tank, along with several anemones. I have to say everything had been running great! I only have to clean the glass about once a week. Everything in the tank seems to be very happy with the current bio load. I have been doing water changes about once every 2 months (I know i should be doing it more) [not really]. As far as i can tell the turf scrubber has been a success for me and when i move i plan on adding one to my 120g display tank. However, I will not be going skimmerless on the 120g display."

Redwing on the CR site: "I set [my scrubber] up to remove algae from my display tank (and that is exactly what it is doing). But I now I have noticed that my skim-mate is much darker and that I do not have to clean it as much (about once every week not every other day). also like I posted my nitrates have never been undetectable (more like 5+ ppm) so if you ask me [the scrubber] is doing exactly what it is supposed to do. Could I take my skimmer offline maybe but I most likely will not I like knowing that I have backup if something fails [except, skimmers don't remove ammonia, so they won't help]. also my skimmer is a CL125 and I have more than 160 gallons in my hole setup so my skimmer has always been way undersized. (most people would use a skimmer twice that size for this many gallons)"

Mrbncal on the scrubber site: "I have a 75 w/ 30 gallon sump and ran w/o a skimmer for over a year BEFORE I found out about ATS'. There were some things that didnt do well, but anenomes and zoas, most lps did great, montis and a few acros grew fine w/o a skimmer. Bubble algae and hair algae did great also. Since I started running a screen covered in algae my tank has never been healthier. Its been 6 mos or so maybe 7, I have NO hair algae and the bubble algae is losing ground. Almost gone completely. I feed a ton of frozen and oyster feast. I should probably back off some feedings but the coco worms love life and the gorgonians are growing, so why change anything."

Tien on the MFK site: "So I have been running a scrubber on a test tank with goldfish. At one point nitrates were near 80 ppm (I know this is WAY high, but I did this intentionally with the goldfish). I have done no water changes, and my nitrates are now about 7 ppm! and nitrites are zero. I do not have the best set up with lighting yet and the scrubber set up only cost me $25, but it works with fresh water! [yes scrubbers work just as well with FW]. I am going to continue to add goldfish and overstock the tank to see how the scrubber handles it. Looks like I will be building a large scrubber system for the 500 gallon!"

Billy_m24 on the MFK site: "my algee scrubber is working, I finally have purple on my rocks! I have 175 reef tank with 2 400w MH light and 2 blue vho, my nitrate was always very high in the red zone, and now after 2 month [of using the scrubber] I'm running about 10 on the nitrates and I have purple [on the rocks], and my ph stays at 8.2"

PRC on the LR site: "I use a scrubber on a 180g tank, that I upgraded from a 90g tank. Neither ever had a skimmer. I ran across this [scrubber] thread when I was initially cycling my tank, I set it up according to specs, I've never had 1 piece of algae in my tank. I, like everybody, get the usual dusting on the glass that gets brushed off. But I've never had algae, and I've never had nitrates above 5ppm. I feed alot because I've got big fish with big appetites. I also have very little clean up crew. I panicked when I first set mine up because I didn't think it was working. I just left it, it started to work and has kept my tank very stable. Just tweek it a little and give it time. It doesn't take control of the system overnight, but once it does it keeps it very stable....on top of that it only takes about 5 minutes to clean once per week. I'm so naive when it comes to algae issues that when I read a thread about hair algae, I automatically assume that somebody is just neglecting there tank terribly because I've never had to deal with it."

Renman303 on the MD site: "I have been running a 4-sheet (8 1/2" x 11") ATS since June '09 with not only no ill effects but, my water is crystal clear! I have unhooked my Deltec AP851 Protein Skimmer in July of '09 (anyone want to buy it?) and have been running solely on the ATS since then (~15 months). I scrape one side of each of the 4 sheets once a month [needs more often!]. I add no chemicals of any kind to the water and only do a 10 percent water change once a week. Salt is much cheaper than chemicals. I don't even use RO/DI water any more. I just run through Carbon as Phosban prior to mixing. Simple....as it should be!"

Vannpytt on the scrubber site: "I'm experiencing massive amounts of live particles in my water. When the lights go out, and I turn on a flashlight, I can see with my bare eyes 1-3mm long shrimplike creatures swimming in the water, jumping on the stones. It's amazing, while the water is so clear, there are still so much life. I'm also experiencing massive critical comments from the local forums claiming I'm destined to fail etc. I still have no values measurable of ammonia, nitrite, nitrate nor phosphate. The pH is fine as well as the salinity. The algae growth [in the tank] that came initially, is slower, and I added 2 lawnmovers to take care of the rest. Coraline is spreading on the live rocks, I added a Sun Coral who seems to be happy, as well as some Zoas."

Vykhang on the scrubber site: "After 4 yrs, it has become so hard to maintain my 300 gal reef/fish tank due to nitrate and phosphate. Just doing 10-15 percent water changes on 300 gal tank per week is driving me crazy not to mention salt cost. After seaching the net and came across this website, I've started my own version of scrubber. It has been running over a year for me and I've not changed (add only) water since (I don't belive in changing water if all chemicals are in spec. The scrubbers are 1" above the water line to minimize the water noise [would be even better to have the screens in the water]. Water line is maintained by electronic sensor. Can't speak for everyone but the results has been absolutelly wonderful. Nitrate and Phosphate are un-detectable. I can't thank Santa Monica enough because little to no water changes. I just maintain chemical additives and add water to my reserve tank."

Yesman on the scrubber site: "I clean it all off completely every 7 days. However as you can see with over 3 pounds in weight of algae every 7 days being scraped off the screen and with nitrates and phosphates at zero, it may be ok to clean this way. Interesting to note that at the bottom of the acrylic box, the water level is about 3 inches with algae growing all over the acrylic and alive with pods, even some amphipods!"
 
Cleaning Guidelines:

Black/oily growth, but no green: Clean every last bit of it off every three days.

Dark brown growth, but no green: Clean all of it off every 4 days.

Light brown growth, but no green: Clean most of if off every 5 days.

Mostly brown growth, but some green: Clean all of the brown off every 6 days, but leave some of the green.

Half brown and half green growth: Clean most of it off every 7 days.

Mostly green growth: clean most of it off every 10 days.


In all cases, stronger lighting will help you get to green faster, even if the extra lighting is only temporary.

Also, when there is lots of green, you are getting the most filtering. So to minimize nutrient spikes which might occur after cleaning the green off, consider cutting the screen vertically into two halves, and cleaning only one of the halves every 5 days. This give 10 days of growth for each half (about the max you can go), but always leaves the other half to do the filtering.

After several months, you may start getting some thick brown algae that feels like fuzz, and it won't come off. That's turf algae. You don't want turf because it's thick and dark, and it blocks light from reaching the screen (also, because turf does not grow fast enough to be a good filter.) Scrape the turf off with a hack saw blade. Matter of fact, if you start getting turf, you can just start doing all your weekly cleaning with a hack saw blade.
 
i may give this a go one day, glad to see it worked for you! :hyper: shame for a lot of us we dont have such luck with our tanks. I like the way you are now using all natural methods of filtration, will have to give this a stab soon!
 
Here is the micro table saw that I use to cut the slots in the pipes:
http://www.pennstateind.com/store/MTS3.html

It comes with two blades, and if you put them together like a pancake the thickness will be perfect for a 1/8 inch slot for a single layer of plastic canvas. I've cut about 20 slots and the blades are just starting to need replacing. There are other similar micro saws if you search for them ("mini table saw", etc), as well as some slightly larger "mini" table saws which get a bit expensive for just cutting pipes.

MicroSaw.jpg
 
Here is what it seems the 25 is going to look like. The pink part on the top is the lid. The open part on the front is where the bulb and ballast go. The bottom is open, and will sit on a 5-pound metal plate. The back side will have the water tubes and drains:

25-sketchup1.jpg
 

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