Hardness is often just as important, if not more so than pH. Unless you are dealing with certain wild caught species, or breeding certain species acclimating fish to a different pH than found in the wild is no big deal. Most pH ranges found are associated with the location where the fish is found in the wild. Many species are kept and/or bred in levels different from this.
If you are looking to breed or keep some of the more difficult species consider buying a RO system. Adjusting tap water is difficult & hard to keep consistent in all but the softest of water supplies. By adding anything to the water, peat, chemicals, and the food & waste products associated with fish you have to be concerned with total dissolved solids, which is another aspect of water.
Your water hardness is a component of TDS, generally a higher pH shows a higher hardness level. Hardness stabilizes pH, so using peat, chemicals, or whatever to drop pH it will rebound to near the original pH level in a short amount of time. Starting with RO gives you a blank slate so to speak, you can adjust the pH, hardness to stabilize that pH, and have much more consistent water parameters.