Lava Rock

IMO, not a good idea. Some lava rock can harbor and release toxins into the environment, it's exceptionally difficult to keep clean, and offers no buffering capacity to the tank...
 
Lava rock, I assume you mean volcanic (igneous stuff)....I wouldn't - it can contain heavy metals and other minerals which could leach out into the water. However, the high pH of a marine aquariium can mitigate this - metals leaching out is much more of a problem with acidic water.
 

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