The Geophagines are out, because they are eartheaters. You can't keep Acarichthys, Geophagus, or Satanoperca in a carpet tank. You're also going to have a hard time with a centrepiece if you design the tank like the photo. It's a completely bottom oriented design. Any large fish that rises to the surface area will also shut down its colours because it would be exposed to predation.
The tank also has no centre. The moss rises in the middle (beautifully), and with the exception of hatchetfish or tiny rocket kilies (E annulatus), most fish will want to stay below the highest point of growth. You have this shape ^. A centre needs this shape V. There's nowhere for the 'piece' to fit.
Some Rainbows - trifasciata, boesemani, sexlineata,
http://rainbowfish.angfaqld.org.au/Melano.htm as you'll see on this excellent site can blow ugly little discus out of the water, as can cardinal tetras in huge groups and a lot of killifish. Don't even look at linebred Discus, as over-rated, sickly beasts (okay, I'm being a troublemaker).
We automatically think larger species when we get larger tanks, but my nicest large taank had a tetra community with 50 cardinals in it, along with some large wild caught angels. I had to rehome the fish as I'm moving, but I'm going to do it again when I'm settled, minus the angels.