Hi and welcome to the forum
How long has the tank been set up for?
If less than 2 months I would suggest you reduce feeding to 2 times per week and only feed the fish a bit of food. They should eat it all in 20-30 seconds.
Do a 75% water change and gravel clean the substrate 4-8 hours after feeding.
Monitor the ammonia and nitrite levels and do a 75% water change and gravel clean the substrate on any day you have an ammonia or nitrite reading above 0.
*NB* Make sure any new water is free of chlorine/ chloramine before it is added to the tank.
Get couple of new buckets and use a permanent marker to write "FISH ONLY" on them. Use these buckets for the fish and nothing else.
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What sort of filter do you have on the tank?
Established filters that are more than 2 months old should be cleaned at least once a month and every 2 weeks is better.
If the filter is less than 2 months old then do not clean it at all unless the water flow slows down.
When you clean power filters, you squeeze the filter materials out in a bucket of tank water. Then wash the filter case and impellor assembly under tap water. When its clean, reassemble and fill the filter with tank water and turn it back on.
If you have a filter that "needs the filter cartridges replaced regularly", add some sponge from another brand of filter and don't bother replacing the cartridge for the first 2 months. Then after 2 months you can throw the cartridge away and don't bother replacing it. Just have sponges in the filter.
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If you can give us the tank dimensions (length x width x height) it will also help us advise you on what fish are suitable for it.
If you can contact your water supply company (via website or telephone) and find out what the general hardness (GH) and pH of your water is, it will help with stocking the tank.
If your water is too soft (lacking minerals) the mollies won't do well. Mollies need a general hardness above 250ppm and a pH above 7.0. The rest of the fish you have require soft water with lower GH (less minerals in the water).
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Silver dollars and yoyo loaches are schooling fish that need to be in groups of at least 6 and preferably more. Silver dollars also eat plants and grow too big for your tank. I would suggest returning the one you have.
re: the baby parrot, I assume this is a parrot cichlid?
If yes, then return it because they grow to about 6 inches and will probably eat the tetras and gourami (depending on what type of gourami).
What sort of gourami do you have?
What type of pleco do you have?
Some plecos grow huge (2 foot long) and will not be suitable for your tank. Other species are smaller and will be fine. If you're not sure what type of fish you have, post a picture of them and we can identify them for you.
The black tetras should be kept in groups of 6 or more and preferably 10 or more. Same with the tiger barbs. Depending on the species of fish (black tetra) they could be peaceful or fin nippers. If they are black skirt or black widow tetras they are fin nippers. Post a pic of them and we can ID them for you.
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If any of your fish look off colour, get sick or die, test the water for ammonia and nitrite and do a 75% water change and gravel clean the substrate immediately. Then post a picture of the sick fish here, along with the ammonia and nitrite readings.
Do not treat fish with chemicals unless you know what is wrong. Do water changes first and post pics asap.
There is more information about what to do if your fish get sick, at the following link. It is pretty long and boring but worth knowing. I recommend printing it out and reading it in bed to help fall asleep.
http://www.fishforums.net/threads/what-to-do-if-your-fish-gets-sick.450268/
If you have any questions, feel free to ask and we will do our best to help.