Hi
I can see you are in the UK so the water temperature rise cannot be due to an outside heatwave! The answer is probably a malfunction of the heaters thermostat.
I would take the heater out immediately and replace it. You could try turning the temperature knob from max to min a couple of times then return it to the correct temperature to see if it unsticks it but, to me, the relatively cheap cost of a new heater over loosing stock is a 'no brainer'