Help! - Low Ph And Fish Deaths

I agree with TTA's assessment, but I would add a real caution.  As I said, I have experimented with crushed coral (in two different tanks), dolomite (in three) and aragonite (two tanks).  I also have very soft water with basically no KH.  Both GH and KH are 7-8 ppm which is less than 1 degree.
 
These substances all raised the pH fairly rapidly and significantly.  The dolomite was used when the tank water was at or below 5, and it raised it to 6.4 to 6.8 within a couple days.  This was back in the 1990's so I can't be more specific.  I did not test GH/KH back then.  And the tap water itself had a pH around 5.  More recently, within the past five years, I experimented with aragonite and crushed coral separately.  The aragonite is the better of the two because it like dolomite includes magnesium as well as calcium, whereas crushed coral is calcium.  This time, I knew soda ash was being added to the tap water to give a regular pH around 7, which lowered to around 6 in the tanks I was experimenting on.  Both substances sent the pH soaring within a few days (3 or maybe 4 I believe), from around 6 (possibly below) to 7.6 and 7.8.  I was using about three tablespoons in the filter of the 115g tank and the 90g tank, so very little did a lot.  I cut this down to 2 tablespoons after a major water change, but it didn't lower the pH.  I removed the substance, and the pH returned to normal over several days with normal water changes.
 
TTA and I have discussed this a bit, and it is likely the very low GH/KH providing no buffering that allowed the pH to rise so fast and by so much.  So I would just caution you to go very slow with very little.  And I would recommend aragonite as preferable for both minerals.  Plants need magnesium as well as calcium, so this will benefit more.
 
Byron.
 
Byron said:
TTA and I have discussed this a bit, and it is likely the very low GH/KH providing no buffering that allowed the pH to rise so fast and by so much.  So I would just caution you to go very slow with very little.  And I would recommend aragonite as preferable for both minerals.  Plants need magnesium as well as calcium, so this will benefit more.
 
Byron.
 
I'll add that the lower the pH the faster the dissolving process will take place.  
 
I would like to note there is a very large difference between the solubility of calcium and magnesium. I run 2+ cups of crushed coral on changing water and the TDS barely moves, maybe 20 ppm tops in almost a day. Running more or longer doesn't do much better. The next day I add to the water if a tablespoon or two of Epsom and the TDS jumps another 100+ ppm right away. Then I add a teeny pinch of baking soda and I get maybe a .1 rise in pH and another 15 -20 ppm of TDS.
 
I went through this on another site relative to doing dry and rainy seasons. There are a few scientists who are member and they taught me a lot in this respect. I actually jjst posted in the thread after 4 years. I wanted to come full circle and include information on how things ultimately worked out. I tend to do that in old threads when it acts to finalize them. I hate threads where you never know how things ultimately worked out. http://www.planetcatfish.com/forum/viewtopic.php?f=5&t=33073
 

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