Glue

For gluing things together that are meant for aquarium use, I would always use aquarium sealant. Not only can you reseal aquariums with it, it's great for gluing rocks and things together for tank decorations. I saw a post on here not too long ago where a guy used to it to glue pieces of slate together to act as a cave for his fish. It was pretty kool.
 
I think i have read here that Superglue is safe to use.

superglue gel is i believe.

I'd just stick to aquarium silicone personally, we've used it for building caves before.
 

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