It is important that you use 4dkh or 5dkh solution, DO NOT use aquarium water, as this contains other acidic substances, which can affect the reading (hence why the ph/ kh CO2 tables are inaccurate!)
As the CO2 gasses off from the aquarium into the drop checker, the ph lowers due to the carbonic acids formed by CO2 when it dissolves in water. When the drop checker turns from blue, to green, this indicates a pH of 6.6, and because we know the solution is 4dkh, this tells us we have approximately 30ppm of CO2 in our tank water.
I am now confused, in the origanal post it gives a link to an ebay site (which I have bought of before) for a cheap drop checker, on there they say to add to the solution a small amount of aquarium water but in the original post it says do not do this, so which way do i go, I have ordered that drop checker with the test solution so what do I do?. I am not a chemist and am mainly going on the excellent advice that is given on here, but I am confused.
Add 6g of pure Sodium Bicarbonate to 5l of DeIonised water (DI) to give you a solution at 40dKH.
Mix 10ml of this solution with 90ml of 'fresh' DI to give you 1l of 4dKH reference solution.
Add 4dKH solution, I know I am going to say that as it is my guide lol so you can wait for someone else to reply if you like