Yeah, in principle it's great, a byproduct source of distilled water. Problem is the way it does it, cool the air and see what condenses, which won't always be entirely water. For distilled water you'd select out by boiling point to get pure water, in this case it's whatever happens to be in the air. If it's mainly water then it's all good, if it's not then you've no idea. Ammonia is relatively volatile, so if it's present in the house then it's no great surprise to find it in the dehumidifier. For us it'd be household cleaners to blame for that one.
I played with it once, dumped some daphnia in it, 2/3 water from their tank, 1/3 dehumidifier. With them all dead in 20 minutes I chucked the lot out.