On the shrimp...most habitats of tropical aquarium fish have crustaceans present, and this is a natural food for fish. Depends upon the size of the fish and shrimp of course, and sometimes other factors in the aquarium (well-fed fish tend to be less likely to see other critters as food, generally). I've only once had shrimp, and they were two that came in the bag with pygmy cories so not intentional, and they lived several months with the cories but the shrimp were about the same size as the cories, and there were lots of hiding places. Pygmy cories are not that predatory as other fish might be either. Others who have more experience with shrimp will be able to offer better advice.
Let's take the GH as 8 dGH, that's not bad at all. Call it moderately soft. Plenty of options to explore.
Thinking about the centrepiece...solitary fish that would fit this tend to be sedate, and this is getting back into the problem of the activity of the danios and barbs. Centrepiece might include cichlids (something like a Bolivian Ram), gourami (a small group rather than lone fish) like the Pearl.
The Bristlenose will not be all that obvious, remaining on wood or plant leaves. If you're looking for a centrepiece that will be seen, it won't be a plec.
No, Betta are not community fish, that is only asking for likely trouble (even if lucky to be one of the exceptions) and not fair to the fish.
This is a 60g, but what is the length?