It has been proven that airstones do not add any viable amount of oxygen to the water and CO2 has no relationship to the amount of O2 in the water.
What you need to watch for is an overdose of CO2, but if you do it right this will not happen.
When I say do it right I mean add 1 bottle, monitor for the amount of CO2 being produced into the water, add the second bottle, monitor again. You can get a good gauge of what each is adding so you know when you are getting close, but most people don't go over 3 bottles and on a tank that size 2 should be enough to get a reasonable level.