Frogs should be kept in their own tank for several reasons. If the fish get sick, the medications used to treat them usually kill the frogs. Frogs eat anything small enough to fit in their mouth and that includes pygmy catfish. If catfish get eaten, they extend their pectoral (side) fins and get lodged in the mouth or throat of whatever tried to eat it. Then both fish/ organisms die.
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Mollies don't do well in soft water.
What is the GH (general hardness), KH (carbonate hardness) and pH of your water supply?
This information can usually be obtained from your water supply company's website (Water Analysis Report) or by telephoning them. If they can't help you, take a glass full of tap water to the local pet shop and get them to test it for you. Write the results down (in numbers) when they do the tests. And ask them what the results are in (eg: ppm, dGH, or something else).
Depending on what the GH of your water is, will determine what fish you should keep.
Angelfish, discus, most tetras, most barbs, Bettas, gouramis, rasbora, Corydoras and small species of suckermouth catfish all occur in soft water (GH below 150ppm) and a pH below 7.0.
Livebearers (guppies, platies, swordtails, mollies), rainbowfish and goldfish occur in medium hard water with a GH around 200-250ppm and a pH above 7.0.
If you have very hard water (GH above 300ppm) then look at African Rift Lake cichlids, or use distilled or reverse osmosis water to reduce the GH and keep fishes from softer water.