Everything good on day 2 no visible squabbles
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While each fish is different typically Nijsseni like large territories - up to a square foot. They might recognize this isn't possible or they might insist to the best of their ability. Also that third wheel is gonna have to go to the other side of the tank or the top to be safe - again each fish is different however if you see the extra female trapped somewhere in a corner or the top of the aquarium do her a favor and move her somewhere else.The angel will probably never bother the njisseni. It's the old niche story - angels are not bottom oriented. It's the acaras and cupido that could become testy. None are cave spawners like the njisseni, so maybe it'll work out. I hope so.
I never needed tannins with that species. I know you aren't into breeding, but they bred at pH 6.6 - 6.8, as long as the water was soft (I think around tds 40 - it's been a while since I kept them). The tank water was clear, and they didn't seem to care about lighting. If they do get "reproducey", the colours of the courting females are very nice indeed.