I once looked at using dehumidifier water in my steam iron. When I saw the bits of dust floating in the water, I didn't bother. I know the filters have improved over the years but I'd take a good look at the clarity of the water before considering using it.
In theory, water from a dehumidifier is the same as distilled water - it's water vapour which has been condensed, it's just missing the evaporation stage. So there should be zero GH and KH and a pH of 7.0. Since you have non-zero GH and KH, albeit very low levels, and pH below 7, I would wonder what is in the water. Air borne contamination (eg the dust in mine)?