Fish will also act nervous and skittish, and hide when you enter the room if they aren't use to things moving around them. This happens a lot when aquariums are in bedrooms and the only time you go into the room is to feed them or go to bed. The fish see you enter the room and think predator, and they take off and hide.
To fix the problem (besides what Byron suggested) you can have a small television on in the room. You don't need the sound but the flickering lights and movement on the screen will help the fish get use to movement around them.
You can also use a small oscillating fan with some streamers tied to the front cage. Make the streamers about 12-18 inches long and just let them wave about as the fan blows. Having a mobile in the room with the fan can also add movement.
Using these in addition to floating plants and a picture on the back of the tank will make a huge difference to the fish and you should eventually be able to walk into the room and the fish will continue swimming out in the open.