Is it slimy? It looks a lot like cyanobacteria to me. I am battling cyano right now. It snuck in on some live plants that I got.
I have gotten rid of it before using manual removal and some antibiotics. I am not positive it won't hurt the fish in large quantities, but a small amount won't hurt.
There is a great pinned article in the planted section about different kinds of algaehere. Maybe that article will be of more assistance.