trying to find out all the info i can for ya!
Lowering the pH: The pH can be lowered by using a pH-lowering chemical (available at pet shops). Be aware that many pH-lowering products use phosphate-based chemicals. Phosphate is a nutrient that encourages algae growth. The pH can also be lowered by plants and fish during respiration, when CO2 is exhaled into the water. In hard water, the pH may be difficult to lower. First, soften the water by peat filtration or reverse osmosis, and then try lowering the pH.
If you live near any freshwater rivers or streams, go down and check them out and look for any driftwood, branches 1/2" in diameter, roots from trees, stuff like that. Driftwood, ie wood that has been immersed in water for several weeks is a great source of a chemical called tanic acid, which can naturally lower your pH. It may turn your water a light yellowish brown, but that's okay.
Best bet, is if you find any, first clean it. Scrub it off in a sink or with a hose to remove any dirt or nasties. Then do one of these 3 things to sterilize it.
1. Place in a bucket with a 1:4 ratio lukewarm water and bleach. Let soak 20 minutes, then rinse off, and refill bucket with hot water and dechlor and let soak again to ensure bleach is neutralized.
or
2. Boil wood for 20 minutes, or let wood soak up water and place in oven @ 200F for 2 hours.
or
3. Steam wood in pot for 10 minutes, flip over and steam again for 10 minutes.
All 3 methods will help kill any bacterias on the wood, which you definatly don't want in your tank. Once cleaned, fill a bucket with water you use to fill your fish tank with, and place the wood in it. Let sit for 48 hours. Test the pH of the water every 12 hours to see if a change in the pH happens.... if so, you can use the wood to lower your pH naturally.
Hope this all works for ya!