I think that the "problem" with your pH is your oxygen (air) pump. This is causing the oxygen gas levels (along with other gases in the air) in your tank to go up (obvious). But the problem with this is that it is competing with the carbon dioxide gas in your tank. The oxygen (and air) is replacing the carbon dioxide (This deals with partial pressures in a volume, I won't go into that). This affects your pH because the carbon dioxide is in an equilibrium with carbonic acid in your tank. The more carbon dioxide you push out, the less carbonic acid that can exist and therefore the higher your pH is going to go.
I don't know how large your tank is or how essential the air pump is (if you have a filter that is causing a break in the water surface through its water flow, then you might not need the pump) but you might want to lose the pump if you really want to lower the pH. Others have given you many ways to lower the pH, but I don't think that any will be too effective till the oxygen pump is removed, or at least regulated. The baking soda is just a buffer (not absolute acid nor base), and therefore will try to get your water towards a neutral pH. In your case it might lower the pH but I don't know how much. I personally would recommend against this because you will be raising the KH of the water and this will prevent fluctuations in pH (good) but this will also make your water harder and your fish may not react well to this.
I guess my long-winded recommendation would be to remove the oxygen pump if you want to lower the pH, but I would not try to mess with it too much. If your fish are happy with the pH that you currently have them in, then why change it? However if the fish start to have problems or you are thinking about getting some sensitive fish then I might think about adjusting the pH. For what its worth, if you do remove the oxygen pump the pH will begin to lower but only with some water changes and time. Because of this I think that this would be a good way to both lower your pH and doing it slowly so as not to shock the fish.
I guess you have to ask yourself if you will be suffocating the fish without the air pump and if the fish will be happier in a lower pH. Good luck with whatever you try and keep us posted on what you do try and tell us how it's going.