I also cannot see any connection between the single IA leaf and nitrite.
On the pH, this too is not likley the leaf. You must know the GH and KH as well as the pH of your source water, as these three are very closely connected. A shift of 1, 2, 3 or even 4 decimal points in pH is more likely due to the diurnal fluctuation than the leaf. But you/we need to know the GH and KH to go further.
When testing tap water for pH, you must ensure any dissolved CO2 is outgassed, as this can give a false reading. Not needed for tank water, just fresh tap. Let a glass of water sit 24 hours, then test. Brisk agitation will also dissipate most of the CO2.
It is normal for an aquarium to slowly become more acidic. The extent this occurs depends as I said on the initial GH and KH and pH. And other factors like plants. Everything in an aquarium is interconnected, which is why it is so dangerous to mess with any one parameter, not that you intend to, but don't.