Help! Tank Heater Broke!

I don't know of any heaters that have mercury in them. Certainly no heaters that have been built during the last 10 yrs should have mercury in them.
You can do a water change if you like but I have had heaters break in tanks and never caused a problem to the fish.
 
have done this a few times myself, dont worry, just make sure there are no small shards of glass fallen off and, dont try to repair it :(
 

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