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You have the sponge filters first. After that I would put polywool, then bio media then any chemical filtration you may use (carbon, phosphate/nitrate removers, etc). i would then put a bit more polywool at the top as a final "polish".
Basically you want the mechanic filtration first (sponges and filter wool) to get any sediment out of the water and stop the rest of the media clogging. Then you want your bio filtration and after that you want to put in anything else you might use.
Ahh ok
Personally unless you have a specific issue with water quality you don't need any chemical filter media. Just mechanical media (sponges and filter wool) and something for your bio media. On the bio media there are loads of different options. Basically you want something that the water can flow through easily with a lot of surface area. I normally use the Fluval Bio max ones but there are other alternatives.
One last tip is that some LFS and many websites will say you need to replace the sponges or bio media regularly. This is complete rubbish and is likely to do a lot of damage as you will be removing the bacteria that process the ammonia and nitrite. The only thing you will need to replace is the filter wool, just give the sponges and bio media a rinse off in tank water every so often to remove debris. Dont use tap water though as this will kill of the bacteria.