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Happens to me all the time .He then waded into technical jargon and my eyes glazed.
I also find that portions of originally flexible tubing that get even indirect sunlight or are anywhere near my light fixtures become discolored and rigid, even when dry. I can pretty much indefinitely reuse any tubing that has stayed dry, cool, and in the dark.I am not so sure the problem is in the airline but rather has to do with what happens to it in tank water. Consider how many new types of chemicals we use in tanks. Buffers, fertilizers, dechlor that does more than just that. The contents of the foods we feed has changed as well.
I changed over my pleco space some years ago from mostly hang-on filters and pump powered Mattens filters to a 100% air driven system using one of the pricey Jehmco piston pumps. Th system is not large. It has 3 racks of 2 tanks each and each rack has its own manifold to provide 6 outlets to each rack. The 3/8 diameter vinyl distribution lines are never in the water and they are doing just fine, Not stiff at all. But the lines which run from the manifolds into the tanks do get stiff and need replacing.
So it is my belief that it is not so much just the line itself which is the problem but rather things which are now common in the water which causes the problem. I use both vinyl and silicone lines. I find the biggest issue with the stiffness is when the line gets detached from whatever it is connected to in the tank. It then becomes difficult to get it back on securely as this requires that the line be flexible. And even when it goes back in place it won't stay that way.