Welcome! I recommend reading on the nitrogen cycle first. After your tank is cycled then you can add fish. So you really need to do some research on the cycling process and you need a test kits, liquid, the dip sticks are not very accurate. You need ammonia, nitrite, nitrate (the main ones) and ph. Other recomendations to have on hand is phosphhate (if you keep plants), calcium, iron, total hardness, general hardness, total hardness, chlorine & chloramines
Be sure to add a water conditoner if you don't. Everyone here suggests prime.
Some suggestions on fish are;
The neons will not be compatible with the angels as they can be quite nasty and eat your neons. I have a 75 gallon angelfish and they are stunning and I keep them only with other angels. So it’s a community angel fish tank, just gorgeous.
You can add one angel (because they get big) and add just a other medium sized fish. Fish that MAY work plays, gouramies, tetras, scissortail, giant danios, cherry barbs and a very mild-mannered cichlid like rams, kribs –only get one of each as if you have a male and female they may start breeding and the crap will hit the fan.
The main problem with mixing fish with goldies is the temperature. Goldies are coldwater fish where as oter fish need heat to thrive.
Personally I would stick to just a goldie tank with a few cherry barbs. You could add another fancy goldie in there and absolutely nothing else. Stay away from the bigger goldies like shubbies, telescopes (they could handle a 20 gallon with out anything in it) and comets.