For the first hour of sunlight in the morning on Earth near the equator, we get mostly yellow light and then the red starts to kick in after that. An hour or so after that the blue and ultraviolet light starts to build up and peaks during the middle of the day for about 6-8 hours. After that the blue decreases and red becomes more noticeable for a few hours before sunset, and then we get about 1 hour of yellow light at dusk.
With programmable LED lights you have two options.
1) You can start off with yellow and red coming on for an hour in the morning. Then add blue and UV if you have UV. During the main part of the lighting cycle you have equal parts of blue, red, green and any other colour you have on the light. About an hour or two before lights out you decrease the blue and run red and yellow for the final hour.
2) You have all the colours set to the same level and have them on 5% intensity for the first 15 minutes. Every 15 minutes after that you increase the intensity by 10-15% until you hit maximum intensity. Then have all colours at maximum level until 2 hours before lights out and gradually reduce the intensity in the opposite way you increased it (reduce intensity by 10-15% every 15 minutes until it gets dull). Then wait 15 minutes and lights off.
With other lights that aren't programmable, you turn the room light on or open the curtain at least 30 minutes before turning the tank light on. Then turn the tank light on.
At night before lights out, you turn the room light on, then turn the tank light off. Wait 30 minutes or more before turning the room light out.
---------------------
Sunrise and sunset normally only last about 1 hour. This is mainly yellow light for the first 30-45 minutes and then red light starts to show.
Blue and UV light is most intense during the middle of the day between 9am and 4pm.
There shouldn't be any light at night after the lights have gone off. The only exception to this is moonlight and that can be white light set at a very low intensity, or better still, have a low wattage light on in the room for a few hours at night, for one week each month. No light at night for the other 3 weeks of the month.
During the main lighting phase the light should appear white, the water should look clear, and there shouldn't be any colour in the water.
---------------------
Any time I have had Zoanthids they get bigger when fed and shrink a bit after they have finished eating. It has been a long time since I had any so maybe things have changed but we always had them under good light so they coloured up from the symbiotic algae.