Is the fish breathing heavily? She looks like she has flared gills in the picture and that could indicate gill flukes are causing some issues to her.
She also appears to have a few unusual marks on her body and they could be from another fish biting her, however that is unlikely considering there are only mollies and guppies in the tank. It is more likely a protozoan infection.
Gill flukes and most protozoan infections can be easily treated in live bearers by adding salt (sodium chloride). Add 2 heaped tablespoons of aquarium salt, rock salt, swimming pool salt or sea salt per 20 litres of tank water. If there is no improvement after a few days you can double that dose. Keep the salt level high for at least 2 weeks then do small 10% water changes each day for a week to dilute the salt. Then do normal water changes after that.
Before you add the salt, do a 75% water change and complete gravel clean, wipe the inside of the glass down, and if you haven't cleaned the filter in the last month then do that too. Wash filter materials in a bucket of tank water.
Make sure any new water is free of chlorine/ chloramine before it is added to the tank.
To work out the volume of water in your tank:
measure length x width x height in cm.
divide by 1000.
= volume in litres.
When you measure the height, measure from top of the substrate to top of the water level.
There is a calculator/ converter in the "How To Tips" at the top of this page that will let you convert litres to gallons.