How long and wide is a 65gallon tank?
How often do you plan on feeding the fish and doing water changes?
Will the tank be cycled/ established before the fish are added?
How many angelfish did you want? To get a breeding pair you need to buy around 10 young fish and grow them up together, then let them pair off naturally. In a tank that is 6-foot long you can have 2-3 adult pairs of angels, assuming there is lots of plants and wood to break up territories. When the adults have paired off you remove unwanted fish to another tank or sell them.
As stated livebearers need moderately hard, slightly alkaline water so keep your GH around 150ppm and pH around 7.4 if possible.
If you plan on keeping wild caught angelfish then no livebearers should be kept with them and they need soft acidic water.
Platies, keep at least 4 females per male or better still only keep males or females. Male livebearers harass females (and sometimes other fish) and can cause problems. Females on their own are usually happier. Having a group of females with 1 male can spread the harassment around and reduce stress on the girls.
Never put Swordtails with platies because they cross breed. Keep platies or swords but not both. If you choose swordtails keep males or females, or 1 male and lots of females, as mention in platy.
Guppies-6 male, pita and carry lots of diseases. Best left to a species only tank in the kid's room.
No Mollies. Put mollies into another tank if you want them. They NEED hard alkaline water (usually with some salt) otherwise you are wasting your time.
All common livebearers (mollies, swordtails, guppies, platies) are riddled with diseases so quarantine all new fish for a month and treat them all for intestinal worms and gill flukes as soon as you get them.
Corydoras do best in groups of 6 or more. Try to get 10-12 if you can afford it. You can mix different species for more variation, eg: 4 panda cory, 4 peppered, 4 sterbai.
Bristlenose pleco-1 should be fine but you can buy 2 young fish (male & female) and they will usually breed when mature. You can then sell the young.
If you have suckermouth catfish like bristlenose, make sure there is driftwood in the tank at all times.
Don't touch the common dwarf gouramis, they are riddled in disease and just about always cause problems with the crap they bring into tanks.
If you do get dwarf gouramis quarantine them (away from all other fish) for at least 1 month, preferably 2 months before adding to the main tank.
Get a pr of keyhole cichlids. They are fairly peaceful and will breed. Alternatively, 2-3 prs of blue or gold rams, or pr of bolivian butterfly cichlids. Maybe a pr of bolivians and 2 prs or blue rams if you don't want keyholes. You could also look at Apistogramma cacatuoides instead of blue rams.
Kuhli loaches are fine. Get a group so there is more chance of seeing them.
Lemon tetras are fine but get 10 or more for best display.
Rummy nose tetras are fine but 10 or more for best display.
Head and tail light tetras are fine but 10 or more for best display. However, head & tail lights are similar to size and shape to lemon tetras and may not contrast that well. Perhaps get 10 black phantom tetras instead.
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Bioload is all about the food you put in vs the water changes and gravel cleans. The more fish and food going into the tank, the more water changes you do to compensate for the waste produced.
If the tank is 6ft long (not sure about tanks sold as gallons) and has established filters, you could have 2prs of adult angelfish, 2pr of dwarf cichlids (keyholes & bolivians), 30-40 small tetras (rummynose, lemon, h&t lights), 6 khulis, 1pr of b/nose catfish, 10 cories, 6-10 platies or swordtails or another fish similar in size to them.
If the tank is 4ft long then 1pr of adult angels, 1pr of keyholes (or 2 prs of the other dwarfs mentioned), 30-40 small tetras, 6 khulis, 1 pr b/nose, 10 cories, 6-10 platies/swords.
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If the tank has established filters, you can add platies & tetras first, wait a few weeks then add small angelfish, dwarf cichlids & b/nose. Then a few weeks later add cories & loaches.
Get young fish and let them grow up together.
Make sure the fish are bagged separately when you buy them. eg: Don't let the shop put angels and catfish together, and don't let them put all the dwarf cichlids together unless they are young fish.
Bag mature/ adult angels individually, young angels can be put in 1 bag. Tetras can go together. Livebearers can go together in their own bag. Young dwarf cichlids together in 1 bag, but mature dwarfs 1 pr per bag. B/nose in their own bag. Corydoras in their own bag. Khulis in their own bag.