this might be a silly question but what bio medium do you have in your filter , is it possably coral or lime based, as i have know it happen before.
The only media that i'm running is the stuff that came with my Eheim - EHFISUBSTRAT and EHFIMECH, dont think that either of these are lime based.
Need to get some stuff done and then I'll change 50% water to see what happens.
50% water change performed and have to take the wife out so i'll retest in about an hour to see where I'm up to! then we start EI......